발간논문

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Vol.45, No.11, 622 ~ 628, 2007
Title
Smelting & Refining ; Carbothermic Reduction of Ta2O5 by Ar Plasma Arc Melting
김병규 Byoung Gyu Kim , 김원백 Won Baek Kim , 최국선 Good Sun Choi , 서창열 Chang Youl Suh , 임재원 Jae Won Lim , 한만갑 Man Gap Han
Abstract
A Ta metal has been produced by the carbon-reduction of Ta2O5 by Ar plasma melting. Concentration change of oxygen and carbon impurities in the Ta metal produced by the carbon-reduction has been also investigated. It was found that a pure Ta metal without Ta2O5 and TaC could be obtained when the ratio of carbon and Ta2O5(C/Ta2O5) was 5.0. Considering only total oxygen and carbon concentrations, the Ta metal with the purity of 99.85% could be obtained at the C/Ta2O5=5.0. The oxygen concentration in the Ta metal considerably decreased with increasing the C/Ta2O5, and the Vickers hardness of the Ta metal decreased down to about 230~240 Hv with the remarkable decrease in the oxygen concentration, which means that the hardness of Ta metal strongly depends on the oxygen concentration.
Key Words
tantalum, plasma arc melting, carbon-reduction, refining, Vickers hardness, impurity
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