발간논문

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Vol.49, No.12, 950 ~ 956, 2011
Title
Synthesis of Hollow Cu Oxide Nanoparticles by Oxidation
이정구 Jung Goo Lee , 백연경 Youn Kyoung Baek , 정국채 Kook Chae Chung , 최철진 Chul Jin Choi
Abstract
In the present study, the formation of hollow Cu oxide nanoparticles through the oxidation process at temperatures from 200 to 300℃ has been studied by transmission electron microscopy with Cu nanoparticles produced by the plasma arc discharge method. The Cu nanoparticles had a thin oxide layer on the surface at room temperature and the thickness of this oxide layer increased during oxidation in atmosphere at 200-300℃ However, the oxide layer consisted of Cu2O and CuO after oxidation at 200℃ whereas this layer was comprised of only CuO after oxidation at 300℃ On the other hand, hollow Cu oxide nanoparticles are obtained as a result of vacancy aggregation in the oxidation processes, resulting from the rapid outward diffusion of metal ions through the oxide layer during the oxidation process.
Key Words
oxidation, hollow, nanoparticles, interdiffusion
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