발간논문

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Vol.51, No.5, 385 ~ 392, 2013
Title
The Effect of Mg Addition and Manufacturing Conditions on the Interfacial Reactions between Al and CNT in Al-CNT Pellets
임정규 Jung Kyu Lim , 최순열 Soon Yool Choi , 최경환 Kyong Hwan Choe , 김상섭 Sang Sub Kim , 조규섭 Gue Serb Cho
Abstract
In the present study, Al-CNT pellets were investigated to understand the effect of Mg addition and manufacturing conditions on the interfacial reactions between Al and CNTs in Al-CNT pellets. The pellets were heated and held at 700 ℃ and 800 ℃ for 2 hours under nitrogen (N2) atmosphere. To confirm the reactions between Al and CNT in the pellets under different manufacturing conditions, the microstructures were observed by optical microscopy (OM) and field emission scanning electro microscopy (FESEM). And, the composition and reaction phases were analyzed by energy dispersive X-ray spectroscory (EDXS) and X-ray diffractometry (XRD). The presence of oxidation products and Mg on the surface of Al powder in the pellets appeared to prevent the formation of Al4C3. But, Al4C3 reaction products were increased due to the high temperature of 800 ℃, which produced a high amount of reduced aluminium and increased the reaction areas between Al and CNT. The Al-CNT pellets compacted under air atmosphere prohibited the reaction between Al and CNT because of the high amount of oxidation products, such as MgO and MgAl2O4.
Key Words
Al-CNT, Al4C3, Mg contents, N2 atmosphere, oxidation products
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