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Vol.53, No.6, 426 ~ 432, 2015
Title
Recovery of Tin and Nitric Acid from Spent Solder Stripping Solutions
Jae-woo Ahn , Seong-hyung Ryu , Tae-young Kim
Abstract
Spent solder-stripping solutions containing tin, copper, iron, and lead in nitric acid solution, are by-products of the manufacture of printed-circuit boards. The recovery of these metals and the nitric acid, for re-use has economic and environmental benefits. In the spent solder-stripping solution, a systematic method to determine a suitable process for recovery of valuable metals and nitric acid was developed. Initially, more than 90% of the tin was successfully recovered as high-purity SnO2 by thermal precipitation at 80 ℃ for 3 hours. About 94% of the nitric acid was regenerated effectively from the spent solutions by diffusion dialysis, after which there remained copper, iron, and lead in solution. Leakage of tin through the anion-exchange membrane was the lowest (0.026%), whereas Pb-leakage was highest (4.26%). The concentration of the regenerated nitric acid was about 5.1 N.
Key Words
tin, nitric acid, diffusion dialysis, recovery, solder stripping solution
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