발간논문

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Vol.54, No.7, 519 ~ 526, 2016
Title
Properties of a Dye Sensitized Solar Cell using Electrodes with Au Nano Powder Blocking Layers
송정호 Jeongho Song , 노윤영 Yunyoung Noh , 최민경 Minkyoung Choi , 김광배 Kwangbae Kim , 송오성 Ohsung Song
Abstract
We prepared working electrodes with blocking layers containing 0.0∼0.5 wt% Au nano powder to improve the energy conversion efficiencies (ECEs) of a dye sensitized solar cell (DSSC). TEM, FE-SEM, and AFM were used to characterize microstructure. XRD and micro-Raman were used to determine the phase and localized surface plasmon resonance (LSPR) effect of the blocking layer with Au nano powder. A solar simulator and a potentiostat were used to confirm the photovoltaic properties of the DSSC with the Au nano powder. From the results of the microstructure analysis, we confirmed that the Au nano powder had particle sizes of less than 70 nm, dispersed uniformly on the blocking layer. Based on the phase and composition analysis, we identified the presence of Au, and the Raman intensity increased as the amount of Au was increased. The photovoltaic results showed that the ECE reached 5.52% with the Au addition, compared to an ECE of 5.00% without the Au addition. This enhancement was due to the increased LSPR of the blocking layer with the Au addition. Our results suggest that we might improve the efficiency of a DSSC by the proper addition of Au nano powder on the blocking layer. †(Received November 24, 2015; Accepted February 22, 2016)
Key Words
solar cell, coating, electrical properties, atomic force microscopy, localized surface plasmon resonance
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