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Vol.58, No.1, 1 ~ 7, 2020
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| Title |
| Study on the Effect of the Thiourea on Nano-Mechanical Properties and Microstructures of the Electroformed Thin Ni-P Foil |
| Moo Young Jung , Chang Su Nam , Byung-sik Lee , Yong Choi |
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| Abstract |
| The effect of thiourea on the nano-mechanical and chemical properties of Ni-P foil was studied to develop a high performance Ni-P deposit for automobile and machinery parts. The Ni-P deposit was prepared by electroforming in a modified sulphate bath with different amounts of thiourea. Chemical analysis of the electrodeposited Ni-P foils by energy dispersive spectroscopy showed that phosphorous in the foil was reduced with thiourea. Structural analysis by X-ray diffractometry revealed that the (111) plane of the Ni-P deposits grew preferentially with increasing crystallinity. Surface analysis by atomic force microscopy and fieldemission scanning electron microscopy showed that the surfaces of the Ni-P electrodeposited with 0 and 0.01 g/L thiourea were relatively smooth and clean showing no nodules, whereas, the cauliflower-like nodules were observed on the surfaces of the deposits prepared with 0.03, 0.05, 0.07 and 0.1 g/L thiourea. The surface roughness (RRMS) of the deposits increased by addition of 0.1 ppm of thiourea from 6 to 54 nm. Nanomechanical properties of the Ni-P foil such as elastic modulus, hardness and stiffness determined by tribonano- indenter were tended to increase by addition of 0.1 ppm of thiourea from 77 to 156 GPa, 6.6 to 8.9 GPa and 109.6 to 186.6 μN/nm, respectively.
(Received September 16, 2019; Accepted November 30, 2019) |
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| Key Words |
| electrodeposition, Ni-P, thiourea |
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